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DJ GOA. Nawty Loopz. Mr Bishi , Steve Hill , Technikal. As disclosed in a copending, commonly assigned application by S. Gulati et al. In grinding the surfaces of such direct-cast laminated lenses to selected prescriptions for ophthalmic use, it was recently discovered that the hardness of the plastic surface elements, although apparently adequate as measured at the surfaces of the lenses as made, was well below commercially acceptable levels in a boundary region of the plastic layers adjacent to the adhesive bonding layers in the laminates.
For example, at plastic layer thicknesses of 1 mm or less, Barcol hardness values of 71 and below were frequently observed. Since it was anticipated that prescription grinding would frequently involve the removal of sufficient material from the outer plastic elements to approach this thickness, thus exposing the softer plastic of the boundary region, a solution to the problem of low hardness adjacent the boundary region was sought. The present invention is founded on the discovery that the softening of direct-cast diethylene glycol bis allyl carbonate plastic lens elements which occurs adjacent adhesive bonding layers is due to catalyst absorption by the adhesive during or prior to plastic polymerization.
In one aspect, then, the invention includes a method for providing a polymerized diethylene glycol bis allyl carbonate plastic article or element exhibiting enhanced scratch resistance and hardness which comprises polymerizing the plastic monomer by means of a mixed polymerization catalyst. This catalyst consists essentially of a mixture of isopropyl percarbonate and benzoyl peroxide.
Hence the invention further provides a glass-plastic laminated article, such as a lens, comprising at least one direct-cast diethylene glycol bis allyl carbonate plastic surface element bonded to a glass element by a polymeric bonding layer, wherein the cast plastic surface element exhibits a Barcol hardness at least equivalent to the minimum hardness of conventional lenses a Barcol hardness of at least about 77 in regions of the element spaced 1 mm or greater from the polymeric bonding layer in the lens.
The invention may be further understood by reference to the drawing wherein:. The problem underlying the present invention can be more fully understood by reference to FIG. The graph adjacent the drawing of the laminate plots Barcol hardness in the plastic layer as a function of distance from the adhesive bonding layer and suggests that, while hardness values near the outer surface of the plastic layer are at conventional levels, considerably lower hardness in the plastic is observed in regions close to the bonding layer.
Hardness values of 71 and below are shown at distances 1 mm and less from the adhesive. As noted in the aforementioned Gulati et al. The glass may be, for example, photochromic microsheet glass such as described in U. The polymeric adhesive used to coat the glass will depend on the size and configuration of the article, and its intended use.
For ophthalmic lens applications, the use of low elastic modulus adhesive polymers, exemplified by selected polyurethane and highly plasticized polyvinyl butyral polymers, is preferred. Uniform coatings of such polymers can be applied by dipping sheet glass elements to be provided with coatings into solutions of the adhesives in organic solvents. This formulation provides a cured laminated component exhibiting the hardness characteristics shown in FIG.
But thats as far as I have gotten. Is there anything you could recommend as a resource to understand how to do this type of thing so well? Fabfilter had some very brief tutes, but they don't do it like you do!
I checked youtube and you have a 5 hour tutorial but no speaking in it Thanks again - your templates really stand out compared to the others I've heard on this site and generally. Hope to hear you perform someday! I should also say - if you were to record a 'mastering master class' video tute and stick it on producerbox I'd be happy to pay for that, too. Please Sign in to contact this author. New here? Create an account.
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